In a mixed mode file, the background material for an entire NSC group may be defined by the Glass column for the NSC surface in the LDE:

Lens Data Editor - Specifying a Glass on the NSC Surface

Note, however, that because the entry and exit ports serves as an interface between the sequential surfaces and the NSC group, these ports can have refractive power if a non-air glass is applied to the Non-Sequential Component surface in the LDE. 

If this is not a desired solution, yet a “background” material is still desired, then the same solution which is described for a pure NSC system can be utilized in the NSCE of a mixed mode design.